• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:
    Reactor exchanger or exchanger comprising at least 3 stages with on each stage at least one millimetric channel area promoting the exchange of heat and at least one distribution zone upstream and / or downstream of the millimeter channel region, characterized in that the distribution zone upstream and / or downstream of the channel zone consists of a cavity comprising between its floor and its ceiling at most 3 mm, the equivalent diameter of which is less than 3 mm.
    公开号:FR3023494A1
    申请号:FR1456623
    申请日:2014-07-09
    公开日:2016-01-15
    发明作者:Pascal Del-Gallo；Olivier Dubet；Laurent Prost；Marc Wagner；Matthieu Flin
    申请人:Air Liquide SA；LAir Liquide SA pour lEtude et lExploitation des Procedes Georges Claude；
    IPC主号:
    专利说明:

    [0001] The present invention relates to reactor-exchangers and exchangers and to their manufacturing process. More precisely, it is a question of reactor-exchangers and millistructured exchangers implemented in industrial processes which require the operation of these apparatus under the following conditions: (i) - a high temperature / pressure pair, (ii) - minimum head losses; and (iii) conditions that allow for process intensification such as the use of a catalytic exchanger reactor for the production of synthesis gas or the use of a compact plate heat exchanger for preheating Oxygen used in an oxycombustion process. A millistructured reactor-exchanger is a chemical reactor where exchanges of matter and heat are intensified thanks to a geometry of channels whose characteristic dimensions such as the hydraulic diameter are of the order of a millimeter. The channels constituting the geometry of these millistructured reactor-exchangers are generally etched on plates assembled together and each of which constitutes a stage of the apparatus. The multiple channels that make up the same plate are generally connected to each other and passages are arranged to allow the transfer of the fluid used (gaseous or liquid phase) from one plate to another. The millistructured reactor-exchangers are supplied with reactants by a distributor or a distribution zone whose role is to ensure a homogeneous distribution of the reagents in all the channels. The product of the reaction implemented in the millistructured reactor-exchanger is collected by a collector which allows it to be conveyed outside the apparatus. Subsequently, we shall understand: (i) - "Stage" means a set of channels positioned on the same level and in which a chemical reaction or heat exchange takes place, (ii) - "Wall" means a partition wall; separation between two consecutive channels arranged on the same floor, (iii) - By "distributor" or "distribution area", a volume connected to a set of channels and disposed on the same floor and in which / circulates reagents routed from outside the reactor exchanger to a set of channels and (iv) - "collector" means a volume connected to a set of channels and arranged on the same stage and in which the products of the reaction circulate fed from the set of channels to the outside of the exchanger-reactor. Some of the channels constituting the reactor-exchanger may be filled with solid forms, for example foams, for the purpose of improving exchanges, and / or catalysts in solid form or in the form of a deposit covering the channel walls and the elements that can fill the channels like the walls of the mosses. By analogy with the millistructured reactor-exchanger, a millistructured exchanger is an exchanger whose characteristics are similar to those of a millistructured exchanger-reactor and for which we find the elements defined above as (i) the "stages", (ii) "walls", (iii) "distributors" or "distribution zones" and (iv) "collectors". The channels of the millistructured exchangers can also be filled with solid forms such as foams, in order to improve the heat exchange. The thermal integration of these devices can be subject to extensive optimization to optimize the heat exchange between fluids circulating in the device at different temperatures through a multi-stage spatial fluid distribution and the use of several distributors and collectors. For example, millistructured exchangers proposed for preheating oxygen in a glass furnace are composed of a multitude of millimeter passages arranged on different stages and which are formed through channels connected to each other. The channels may be supplied with hot fluids, for example at a temperature of between about 700 ° C. and 950 ° C. by one or more distributors. The cooled and heated fluids are conveyed outside the apparatus by one or more collectors. To fully benefit from the use of a millistructured reactor-exchanger or a millistructured exchanger in the industrial processes concerned, these equipment must have the following properties: - They must be able to work on a high "pressure x temperature" product generally greater than or equal to about 12.105Pa. ° C (12,000 bar. ° C), which corresponds to a temperature greater than or equal to 600 ° C and a pressure greater than 20.105Pa (20 bar); - They must be characterized by a surface area to volume ratio of less than or equal to approximately 40,000m2 / m3 and greater than or equal to approximately 4,000m2 / m3, to allow the intensification of wall phenomena and in particular heat transfer; - They must allow an approach temperature of less than 5 ° C between the inlet of hot fluids and the outlet of cooled or heated fluids; and - They must induce losses of charges lower than 104Pa (100mbar) between the distributor and the collector of a network of channels carrying the same fluid. Several equipment manufacturers offer reactor exchangers and millistructured exchangers. The majority of these devices consist of plates consisting of channels that are obtained by chemical milling spray. This method of manufacture leads to the production of channels whose section has a shape that approaches a semicircle and whose dimensions are approximate and not exactly reproducible from one production batch to another because of the process. machining itself. Indeed, during the chemical machining operation, the bath used is polluted by the metal particles torn from the plates and although the latter is regenerated, it is impossible for reasons of cost of operation to maintain the same efficiency when of manufacturing a large series of plate. Subsequently, the term "semi-circular section" the section of a channel whose properties suffer from the dimensional limits described above and induced by manufacturing methods such as chemical etching and stamping.
    [0002] Even if this channel manufacturing method is not economically attractive, one could imagine that the channels constituting the plates are made by traditional machining. In this case, the section of the latter would not be semi-circular but rectangular type, we will speak of "rectangular section". By analogy, these manufacturing methods can also be used for the manufacture of the distribution zone or the collector, thus giving them geometric priorities similar to those of the channels such as: (i) - Obtaining a radius between the bottom the channel and its walls for manufacturing by chemical milling or stamping and dimension are nonreproducible from one batch of manufacture to another, or alternatively (ii) - Obtaining a right angle for manufacturing by traditional machining . The plates consisting of channels of semicircular or right angle sections thus obtained are generally assembled together by diffusion bonding or soldering diffusion.
    [0003] The sizing of these semicircular or rectangular section devices is based on the application of the American Society of Mechanical Engineers (ASME) section VIII, appendix 13.9, which incorporates the mechanical design of an exchanger and / or a millistructured exchanger-reactor composed of etched plates. The values to be defined in order to obtain the desired mechanical strength are indicated in FIG. 1. The dimensioning of the distribution zone and of the collector is carried out by finite element calculation because the ASME code does not provide for analytical dimensioning of these zones. Once the design has been established, the regulatory validation of the design defined by this method requires a burst test according to ASME UG 101. For example, the expected burst value for a diffusion-bonded and inconel alloy reactor heat exchanger (HR 120) operating at 25 bar and at 900 ° C. is of the order of 3500 bar at ambient temperature. This is very disadvantageous because this test requires oversize the reactor in order to comply with the burst test, the reactor thus losing its compactness and its efficiency in terms of heat transfer due to the increase of the walls of the channels . The manufacture of these millistructured reactor exchangers and / or heat exchangers is currently carried out according to the seven steps described in Figure 2. Among these steps, four are critical because they can cause problems of non-compliance having as sole issue the scrapping the exchanger or the reactor exchanger or plates constituting the pressure vessel if this non-conformity is detected early enough in the manufacturing line of these devices. These four steps are: - The chemical machining of the channels, - The assembly of etched plates by soldering diffusion or diffusion welding, - The welding of the connection heads, on which welded tubes supply or discharge the fluids, on the zones. and the collectors and finally, - The coating operations of a protective layer and / or catalyst in the case of a reactor-exchanger or exchanger subjected to a use inducing phenomena that can degrade the Surface condition of the device.
    [0004] Whatever the machining method used for the manufacture of exchanger or millistructured exchanger-reactors, we obtain channels of semi-circular section in the case of chemical machining (Figure 3) and which consist of two angles straight or rectangular section in the case of traditional machining and which consist of four right angles. This plurality of angles is detrimental to obtaining a homogeneous protective coating over the entire section. Indeed, the phenomena of geometric discontinuities such as angles, increase the probability of generating inhomogeneous deposits, which will inevitably lead to the initiation of degradation phenomena of the surface state of the matrix that we want to preserve as per example of corrosion phenomena, carburetion or nitriding. The sections of angular channels obtained by chemical machining or traditional machining techniques do not optimize the mechanical strength of such an assembly. In fact, the dimensioning calculations with respect to the pressure of such sections result in an increase in the thickness of the walls and the bottom of the channel, the equipment thus losing its compactness but also its efficiency in terms of heat transfer. In addition, chemical machining imposes limitations in terms of geometric shapes such that one can not have a channel having a height greater than or equal to its width, which leads to limitations of the surface / volume ratio leading to limitations. optimization.
    [0005] The assembly of the etched plates by diffusion welding is obtained by the application of a large uniaxial stress (typically of the order of 2MPa to 5MPa) on the matrix consisting of a stack of etched plates and exerted by a press at high temperature for a holding time of several hours. The implementation of this technique is compatible with the manufacture of small devices such as devices contained in a volume of 400mm x 600mm. Beyond these dimensions, the force to be applied to maintain a constant stress becomes too great to be implemented by a high temperature press. Some manufacturers using the diffusion welding process overcome the difficulties of implementing a significant constraint by using a so-called self-clamping assembly.
    [0006] This technique does not effectively control the stress applied to the equipment which generates crushes of channels. The assembly of the etched plates by diffusion brazing is obtained by the application of a low uni-axial stress (typically of the order of 0.2 MPa) exerted by a press or a self-clamping assembly at high temperature and during a holding time of several hours to the matrix consisting of etched plates. Between each of the plates, a brazing filler metal is deposited according to industrial deposition processes that do not guarantee the perfect control of this deposit. This filler metal is intended to diffuse into the matrix during the brazing operation so as to achieve mechanical joining between the plates.
    [0007] In addition, during the temperature maintenance of the equipment in manufacture, the diffusion of the brazing metal can not be controlled, which can lead to discontinuous brazed junctions and which result in a degradation of the mechanical strength of the equipment. . By way of example, the equipment manufactured according to the diffusion soldering method and dimensioned according to the ASME section VIII div.1 appendix 13.9 in HR120 that we realized, did not resist the application of a pressure of 840.105 Pa (840 bar) during the burst test. In order to overcome this degradation, the thickness of the walls and the geometry of the distribution zone have been adapted to increase the contact area between each plate. This has the consequence of limiting the surface / volume ratio, increasing the pressure drop and the poor distribution in the equipment channels. In addition, the ASME code section VIII div.1 appendix 13.9 used for the sizing of this type of brazed equipment does not allow the use of diffusion soldering technology for equipment using fluids containing a lethal gas such as as carbon monoxide for example. Thus, a diffusion bonded apparatus can not be used for the production of Syngas. The equipment manufactured by diffusion brazing is composed "in fine" of a stack of etched plates between which brazed joints are arranged. Therefore, any welding operation on the faces of this equipment leads in most cases to the destruction of soldered joints in the heat affected zone by the welding operation. This phenomenon propagates along the brazed joints and leads in most cases to the rupture of the assembly. To overcome this problem, it is sometimes proposed to add thick reinforcement plates at the time of assembly of the brazed matrix so as to provide a frame-type support welding connectors which does not have soldered joint.
    [0008] From a point of view of process intensification, the fact of assembling engraved plates between them, forces to realize a design of the equipment according to a two-dimensional approach which limits the thermal optimization within the exchanger or the exchanger-reactor by forcing the designers of their type of equipment to be limited to a stage approach to the distribution of fluids.
    [0009] From an eco-manufacturing point of view, all these manufacturing steps are carried out by different business skills and are generally carried out by various subcontractors located in different geographic locations. This results in long lead times and many parts transport.
    [0010] The present invention proposes to solve the disadvantages related to the current manufacturing methods. One solution of the present invention is a reactor-exchanger or exchanger comprising at least 3 stages with on each stage at least one millimetric channel area promoting the exchange of heat and at least one distribution zone upstream and / or downstream of the millimeter channel area, characterized in that the distribution zone upstream and / or downstream of the channel zone consists of a cavity comprising between its floor and its ceiling at most 3 mm and whose equivalent diameter is less than 3 mm.
    [0011] Depending on the case, the reactor-exchanger or exchanger according to the invention may have one or more of the following characteristics: Said cavity comprises a number of supports S at least equal to S = number of channels + 1; - The sections of said millimeter channels are circular in shape; - Said channels of the channel zone are separated by walls with a thickness of less than 2 mm and more particularly between 0.2 mm and 1 mm; Said reactor-exchanger is a catalytic exchanger-reactor and comprises: at least one first stage comprising at least one distribution zone and at least one millimetric channel zone for circulating a gas flow at a temperature greater than 700.degree. that it brings part of the heat necessary for the catalytic reaction; At least one second stage comprising at least one distribution zone and at least one millimetric channel zone for circulating a gaseous flow of reactants in the direction of the length of the millimetric channels covered with catalyst in order to react the gas flow; At least one third stage comprising at least one distribution zone and at least one millimetric channel zone for circulating the gas flow produced on the second plate so that it provides part of the heat necessary for the catalytic reaction; with on the second and the third plate, a system so that the gas flow produced can circulate from the second to the third plate. The subject of the present invention is also the use of an additive manufacturing method for the manufacture of a compact catalytic reactor comprising at least 3 stages with, on each stage, at least one millimetric channel zone favoring the exchange of heat and at least one distribution zone upstream and / or downstream of the millimeter channel region. Preferably the additive manufacturing method will allow the manufacture of a reactor-exchanger or exchanger the distribution zone upstream and / or downstream of the channel zone consists of a cavity comprising between its floor and its ceiling at most 3mm and whose equivalent diameter is less than 3 mm. By equivalent diameter is meant an equivalent hydraulic diameter. Preferably, the additive manufacturing method implements: as base material at least one metal powder of micrometric size, and / or as energy source at least one laser. Indeed, the additive manufacturing method can implement micrometric size metal powders that are melted by one or more lasers to produce finished parts of complex shapes in three dimensions. The part is built layer by layer, the layers are of the order of 50pm, depending on the accuracy of the desired shapes and the desired deposit rate. The metal to be melted can be provided either by powder bed or by a spray nozzle. The lasers used for locally melting the powder are either YAG, fiber or CO2 lasers and the melting of the powders takes place under inert gas (argon, helium, etc.). The present invention is not limited to a single additive manufacturing technique but it applies to all known techniques. Unlike chemical machining or traditional machining techniques, the additive manufacturing method makes it possible to produce cylindrical section channels that have the following advantages (Figure 4): (i) - to offer a better resistance to pressure and thus to allow a significant reduction of the thickness of the walls of the channels, and (ii) - To authorize the use of size rules of pressure apparatus which does not require the realization of a burst test to prove the design efficiency as is the case for Section VIII Div.1 Appendix 13.9 of the ASME Code. Indeed, the design of an exchanger or a reactor-exchanger made by additive manufacturing, making it possible to produce channels with a cylindrical section, is based on "usual" sizing rules of pressure apparatus which apply to the dimensioning of the channels, distributors and collectors with cylindrical sections constituting the exchanger-reactor or the exchanger millistructured.
    [0012] By way of example, the dimensioning of the wall of straight rectangular section channels (value t3 in FIG. 1) of a nickel alloy reactor-heat exchanger (HR 120), dimensioned according to the ASME (American Society of Mechanical Engineers). ) Section VIII, Div.1 Appendix 13.9, is 1.2 mm. Using cylindrical section channels, this wall value calculated by the ASME section VIII div.1 is only 0.3 mm, a reduction by four of the wall thickness required to maintain the wall thickness. pressure. The reduction in the volume of material related to this gain makes it possible (i) to reduce the size of the apparatus with identical production capacity by the fact that the number of channels necessary to reach the production capacity concerned is smaller and thus occupies less space, (ii) to increase the production capacity of the device while maintaining the bulk of the latter which allows to position more channels and thus to process a larger flow of reagents. In addition, in the case of exchanger-reactor or millistructured exchanger made of nickel-rich noble alloy, the reduction of material required goes in the direction of eco-design beneficial to the environment while reducing the cost in raw materials. The techniques of additive manufacturing ultimately allow to obtain so-called "massive" parts which in contrast to assembly techniques such as diffusion brazing or diffusion welding do not have interfaces of assemblies between each etched plate. This property goes in the direction of the mechanical strength of the device by eliminating by construction the presence of weakening lines and eliminating by itself a source of potential fault. Obtaining massive parts by additive manufacturing and the elimination of soldering or diffusion welding interfaces makes it possible to envisage numerous design possibilities without being limited to wall geometries designed to limit the impact of possible defects in the design. assembly such as discontinuities in the brazed joints or welded-diffused interfaces. For example, we can comment on the properties expected to design the distribution area of a reactor-exchanger. By definition, the distribution area of such a device is upstream of the multiple channels in which it distributes the reagents to be treated. The dispensed fluid moves from the dispensing zone to the channels. View of the distribution area, the multiple channels consist of a succession of solid rectangles, walls, and empty rectangles or semicircles, rectangular or semicircular channels. This alternation of solid shapes and empty shapes whose hydraulic diameter is of the order of a millimeter generates a pressure drop which is beneficial to the distribution of the fluid throughout the distribution zone, which has the effect of obtaining a homogeneous distribution of this fluid in all the channels. In order not to disturb the distribution of the fluid in the distribution zone, we intuitively see that the optimal distribution zone is an obstacle-free zone, which is not compatible with the mechanical strength of this zone since it would offer a too much pressure fluid surface which would lead to the generation of a strong stress on the ceiling and the floor of the distribution area. In order to withstand high stresses, two solutions are possible from a mechanical point of view: (i) - Either increase the thickness of the ceiling and the floor of the distribution area, which results in a significant increase in thickness of engraved plates, (ii) - the addition of support such as walls or pillars. The first solution is never used because it increases the thermal resistance between the etched plates. The second solution is preferred and it is implemented in the form of walls because they have the advantage of being less sensitive to assembly defects that are inevitable on an industrial scale. These walls have the disadvantage of greatly disturbing the distribution of the fluid in the distribution zone. The use of additive manufacturing makes it possible to design the reinforcements of the distribution zone in the form of pillars or of any other shape that would not disturb the distribution of the fluid without fear of defects in the assemblies of these pillars with the floor or the ceiling. the distribution zone and thus ensure perfect mechanical strength of this area from the moment the position and diameter of these pillars or shapes have been calculated to compensate for the stress generated by the fluid under pressure. Wall thickness reinforcements from 0.2mm to 2mm fulfill these requirements.
    [0013] The additive manufacturing makes it possible to achieve unimaginable forms by the traditional manufacturing methods and thus the manufacture of the connectors of the exchanger-reactors or millistructured exchangers can be done in the continuity of the manufacture of the body of the apparatuses. This then makes it possible not to perform welding of the connectors on the body and thus eliminate a source of alteration of the structural integrity of the equipment. The mastery of the geometry of the channels by additive manufacturing allows the realization of circular section channels which, in addition to the good pressure resistance that this form brings, also allows to have an optimal channel shape for the deposition of protective coatings and catalysts which are thus homogeneous throughout the channels.
    [0014] By using this additive manufacturing technology, the productivity gain aspect is also enabled by reducing the number of manufacturing steps. In fact, the steps of producing a reactor by integrating the additive manufacturing go from seven to four (FIG. 5). The critical steps, which can generate a scrapping of a complete apparatus or plates constituting the reactor, four in number using the conventional manufacturing technique by assembly of etched plates, pass to two with the adoption of manufacturing. additive. Thus, the only remaining steps being the additive manufacturing step and the deposition step of coatings and catalysts. In summary, the advantages of additive manufacturing over a conventional soldering or soldering solution for chemically etched plates are: - greater process intensification (channel integration, compactness); A reduction in the weight of the reactor or an increase in the volume that is useful for the catalytic reaction; - A reduction in the number of manufacturing and intervention stages located at different sites; - Improvement of the quality of manufacture by ensuring perfect reproducibility; - A process control in the process of being made (how ), Which will reduce the amount of part discarded. A simplification of the design validation according to the ASME construction code As an example, a reactor exchanger according to the invention can be used for the production of synthesis gas. And an exchanger according to the invention can be used in an oxy-fuel combustion process to preheat oxygen.
    权利要求:
    Claims (11)
    [0001]
    REVENDICATIONS1. Reactor exchanger or exchanger comprising at least 3 stages with on each stage at least one millimetric channel area promoting the exchange of heat and at least one distribution zone upstream and / or downstream of the millimeter channel region, characterized in that the distribution zone upstream and / or downstream of the channel zone consists of a cavity comprising between its floor and its ceiling, at most 3 mm and whose equivalent diameter is less than 3 mm.
    [0002]
    2. Reactor-exchanger or exchanger according to claim 1, characterized in that said cavity comprises a number of supports S at least equal to S = number of channels + 1.
    [0003]
    3. Reactor-exchanger or exchanger according to any one of claims 1 or 2, characterized in that the sections of the millimeter channels are circular in shape.
    [0004]
    4. Reactor-exchanger or exchanger according to any one of claims 1 to 3, characterized in that the channels of the channel zone are separated by walls having a thickness of less than 2 mm.
    [0005]
    5. Reactor-exchanger according to any one of claims 1 to 4, characterized in that said reactor-exchanger is a reactor-catalytic exchanger and comprises: - at least a first stage comprising at least one distribution zone; At least one millimeter channel region for circulating a gas flow at a temperature at least greater than 700 ° C so that it provides part of the heat required for the catalytic reaction; At least one second stage comprising at least one distribution zone and at least one millimetric channel zone for circulating a gaseous flow of reactants in the direction of the length of the millimetric channels covered with catalyst in order to react the gas flow; At least one third stage comprising at least one distribution zone and at least one millimetric channel zone for circulating the gas flow produced on the second plate so that it provides part of the heat necessary for the catalytic reaction; with on the second and the third plate, a system so that the gas flow produced can circulate from the second to the third plate
    [0006]
    6. Use of an additive manufacturing method for the manufacture of a compact catalytic reactor comprising at least 3 stages with on each stage at least one millimeter channel area promoting heat exchange and at least one upstream and downstream distribution zone. / or downstream of the millimeter channel area.
    [0007]
    7. Use of an additive manufacturing method for the manufacture of a compact catalytic reactor as defined in one of claims 1 to 5.
    [0008]
    8. Use according to one of claims 6 or 7, characterized in that the additive manufacturing method implements as a base material at least one metal powder of micrometer size.
    [0009]
    9. Use according to one of claims 6 to 8, characterized in that the additive manufacturing method uses as energy source at least one laser.
    [0010]
    10. Process for producing synthesis gas using a reactor-exchanger according to one of claims 1 to 5.
    [0011]
    11. Oxygen combustion process using an exchanger according to one of claims 1 to 5 for preheating oxygen.
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    法律状态:
    2015-06-26| PLFP| Fee payment|Year of fee payment: 2 |
    2016-01-15| PLSC| Publication of the preliminary search report|Effective date: 20160115 |
    2016-07-21| PLFP| Fee payment|Year of fee payment: 3 |
    2017-07-24| PLFP| Fee payment|Year of fee payment: 4 |
    2018-07-25| PLFP| Fee payment|Year of fee payment: 5 |
    2019-07-19| PLFP| Fee payment|Year of fee payment: 6 |
    2020-07-21| PLFP| Fee payment|Year of fee payment: 7 |
    2021-07-27| PLFP| Fee payment|Year of fee payment: 8 |
    优先权:
    申请号 | 申请日 | 专利标题
    FR1456623A|FR3023494B1|2014-07-09|2014-07-09|EXCHANGER AND / OR EXCHANGER-REACTOR MANUFACTURED BY ADDITIVE METHOD|
    FR1456623|2014-07-09|FR1456623A| FR3023494B1|2014-07-09|2014-07-09|EXCHANGER AND / OR EXCHANGER-REACTOR MANUFACTURED BY ADDITIVE METHOD|
    US15/324,843| US20170197196A1|2014-07-09|2015-06-30|Exchanger and/or reactor-exchanger manufactured in an additive process|
    CA2954447A| CA2954447A1|2014-07-09|2015-06-30|Exchanger and/or reactor-exchanger manufactured in an additive process|
    CN201580047047.6A| CN106660008A|2014-07-09|2015-06-30|Exchanger and/or reactor-exchanger manufactured in an additive process|
    PCT/FR2015/051784| WO2016005676A1|2014-07-09|2015-06-30|Exchanger and/or reactor-exchanger manufactured in an additive process|
    KR1020177002782A| KR20170028955A|2014-07-09|2015-06-30|Exchanger and/or reactor-exchanger manufactured in an additive process|
    EP15753963.6A| EP3166717A1|2014-07-09|2015-06-30|Exchanger and/or reactor-exchanger manufactured in an additive process|
    JP2017500867A| JP6622280B2|2014-07-09|2015-06-30|Exchangers and / or reactor-exchangers produced in additive processes|
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